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Homogeneous Catalysis with Metal Phosphine Complexes (Modern Inorganic Chemistry) epub download

by Louis M. Pignolet


The field of transition metal catalysis has experienced incredible growth during the past decade. Homogeneous catalysis suffers from on-site engineering difficulties; however, such reactions usually provide the desired selectivity.

The field of transition metal catalysis has experienced incredible growth during the past decade. The reasons for this are obvious when one considers the world's energy problems and the need for new and less energy­ demanding syntheses of important chemicals. For example, Monsanto's synthesis of optically-active amino acids employs a chiral homogeneous rhodium diphosphine catalyst.

oceedings{ousCW, title {Homogeneous Catalysis with Metal Phosphine Complexes}, author {Louis H. Pignolet}, booktitle {Modern Inorganic Chemistry} . Topics in Current Chemistry. Pignolet}, booktitle {Modern Inorganic Chemistry}, year {1983} }. Louis H. Pignolet. Published in Modern Inorganic Chemistry 1983.

1 Historical Introduction Joseph Chatt

3. Complex compounds. I. Pignolet, Louis . 1943II. The book is intended to provide an up-to-date treatise by experts in the field of homogeneous catalysis with metal phosphine complexes. 1 Historical Introduction Joseph Chatt. The phosphine metal complexes now finding application in homogeneous catalysis are those of the tertiary organic phosphines.

Автор: Louis M. Pignolet Название: Homogeneous Catalysis with Metal Phosphine Complexes Издательство: Springer . It is not by accident that many homogeneous catalysts contain tertiary phosphine ligands.

It is not by accident that many homogeneous catalysts contain tertiary phosphine ligands. Springer Science & Business Media, 21 нояб

The field of transition metal catalysis has experienced incredible growth during the past decade. Springer Science & Business Media, 21 нояб.

3 erized Transition-Metal Phosphine Complexes of Relevance to Catalytic Reactions. 4 Asymmetric Hydrogenation Reactions Using Chiral Diphosphine Complexes of Rhodium. 5 Binuclear, Phosphine-Bridged Complexes: Progress and Prospects. 6 Hydrogenation and Hydroformylation Reactions Using Binuclear Diphosphine-Bridged Complexes of Rhodium. 7 Functionalized Tertiary Phosphines and Related Ligands in Organometallic Coordination Chemistry and Catalysis.

Start by marking Homogeneous Catalysis with Metal Phosphine Complexes as Want to Read .

Start by marking Homogeneous Catalysis with Metal Phosphine Complexes as Want to Read: Want to Read savin. ant to Read.

Homogeneous Redox Catalysis with Transition Metal Compounds in Oxide and Peroxide Systems

Homogeneous Redox Catalysis with Transition Metal Compounds in Oxide and Peroxide Systems. Homogeneous Catalysis with Metal Complexes. Gheorghe Grigore Duca. 2, some theoretical problems of catalysis with transition metal ions or complexes, oxidation of various organic substances with oxidizers such as oxygen and hydrogen peroxide, and also the mechanisms of these processes were considered.

Modern inorganic chemistry. Bibliography, etc. Note: Includes bibliographical references and index. All rights are reserved by their owners. Personal Name: Pignolet, Louis . 1943-. Rubrics: Catalysis Phosphine Metal complexes.

In coordination chemistry phosphines are L-type ligands. Unlike most metal ammine complexes, metal phosphine complexes tend to be lipophilic, displaying good solubility in organic solvents

In coordination chemistry phosphines are L-type ligands. Unlike most metal ammine complexes, metal phosphine complexes tend to be lipophilic, displaying good solubility in organic solvents. They also are compatible with metals in multiple oxidation states. Because of these two features, metal phosphine complexes are useful in homogeneous catalysis. Prominent examples of metal phosphine complexes include Wilkinson's catalyst (Rh(PPh3)3Cl), Grubbs' catalyst, and tetrakis(triphenylphosphine)palladium(0).

Homogeneous Catalysis with Metal Phosphine Complexes (Modern Inorganic Chemistry) epub download

ISBN13: 978-0306412110

ISBN: 030641211X

Author: Louis M. Pignolet

Category: Transportation

Subcategory: Engineering

Language: English

Publisher: Springer; 1 edition (November 1, 1983)

Pages: 489 pages

ePUB size: 1622 kb

FB2 size: 1469 kb

Rating: 4.1

Votes: 400

Other Formats: mbr lrf lit txt

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